When CH3NH2 dissolves in water, it will accept the H+ ion from the water and gets converted into conjugate acid(CH3NH3 +) and produces hydroxide ions(OH). Is an aqueous solution with H3O+ = 8.05 x 10-9 M acidic, basic, or neutral? Quiz 3: volume of solidsnates wrapping a present the gift is a night rectangular prism with a base measuring 15 inches by 12 inches and a height of 8 inches what is the surface area of the git? For example, NaOH + HCl = NaCl + H2O Since both the acid and base are strong, the salt produced would be neutral. Yes, C6H5NH2 is a base because the N atom can accept another proton. HOCl removed H(+) ion. The decrease in electron density weakens the OH bonds in the water molecules and makes it easier for them to lose a proton. J.R. S. Donation of H+, Q:In the reversible equation: * Conjugate base = ? Get a free answer to a quick problem. Q:Complete the balanced molecular reaction for the following weak base with a strong acid: d) it produces few hydroxide ions in water. NH3(aq) https://en.wikipedia.org/wiki/Base_(chemistry), https://en.wikipedia.org/wiki/Salt_(chemistry), https://en.wikipedia.org/wiki/Neutralization_(chemistry). Explain. It would be a basic salt. 8.7: The Acid-Base Properties of Ions and Salts is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts. If you are having trouble with Chemistry, Organic, Physics, Calculus, or Statistics, we got your back! Is an aqueous solution with H3O+ = 1.96 x 10-4 M acidic, basic, or neutral? Write the K_b expression for the weak base equilibrium that occurs in an aqueous solution of methylamine: K_b = _____ Write the net ionic equation for the acid-base hydrolysis equilibrium that is established when ammonium chloride is dissolved in water. Is ch3nh3no3 also an acid or base? Is an aqueous solution with H3O+ = 7.26 x 10-7 M acidic, basic, or neutral? An aqueous solution of CH3NH3NO3 will be Group of answer choices A. basic, because of the hydrolysis of NO3- ions. The equation for AlCl3 is:HCl + Al(OH)3 = AlCl3 + H2OIt is also useful to have memorized the common strong acids and bases to determine whether AlCl3 acts as an acid or base in water (or if it forms a neutral solution).Strong acids: HCl, H2SO4, HNO3, HBr, HI, HClO4Weak acids: HF, CH3COOH, H2CO3, H3PO4, HNO2, H2SO3Strong Bases: LiOH, NaOH, KOH, Ca(OH)2, Sr(OH)2, Ba(OH)2Weak Bases: NH3, NH4OHNote that we are talking about whether AlCl3 is an acid, base, or neutral when dissolved in water.- Salts of strong bases and strong acids: pH will remain neutral at 7.- Salts of weak bases and strong acids: pH less than 7 (acidic).- Salts from strong bases and weak acids: pH greater than 7 (alkaline).Based on these rules, the solution of AlCl3 dissolved in water is Acid.For polyprotic acids (e.g. Is an aqueous solution with H3O+ = 1.83 x 10-8 M acidic, basic, or neutral? First, repulsive electrostatic interactions between the positively charged metal ion and the partially positively charged hydrogen atoms of the coordinated water molecule make it easier for the coordinated water to lose a proton. Lewis, Q:This is for my reviewer please help me with the step by step solution and answer, thank you, Q:Write the products of these reactions. A:Given that: Ionic equilibri. Is an aqueous solution with H3O+ = 4.43 x 10-8 M acidic, basic, or neutral? The nitrogen in C 5 H 5 N would act as a proton acceptor and therefore can be considered a base, but This preview shows page 6 - 9 out of 12 pages. Choose an expert and meet online. Acid-base strength (in Brnsted-Lowry terms) is a relative term: an acid is strong if the position . base, Q:Ethanol can act as either a Lewis acid or a Lewis base (donates or accepts a pair of electrons)., A:Ethanol is an alcohol with two carbon atoms bearing an alcoholic group with a molecular formula, Q:What is the conjugate base of Name of process =, Q:identify the products of the following reactions, a,b and c, A:A chemical reaction is symbolic representation of the conversion of substances to new substances. Q:Methyllithium (CH3Li) is often used as a base in organic reactions. The hypochlorite ion has the tendency to abstract the most acidic hydrogen. But opting out of some of these cookies may affect your browsing experience. The reactions are as follows: \[ NH^+_{4(aq)} + H_2O_{(l)} \ce{ <<=>} HH_{3(aq)} + H_3O^+_{(aq)} \label{16.2}\], \[ C_5H_5NH^+_{(aq)} + H_2O_{(l)} \ce{<<=>} C_5H_5NH_{(aq)} + H_3O^+_{(aq)} \label{16.3}\]. Because not all the molecules of it react with water ions and produce OH - ions, most of them stay together, only, a few molecules do interact with water, Therefore, the amount of OH - ions produced in an aqueous solution . Its conjugate (hydroxylammonium ion) is a weak acid (pka = 5.96). Explain. twice as, A:We have two solutions one is of ph3 and other is of pH 1. d) of its anionic hydrolysis of salt of weak acid and strong base. CH3NH3NO3. SrI2 . Explain. Favorite Answer. Whichever is stronger would decide the properties and character of the salt. A link to the app was sent to your phone. C. NaOH solution 2nd beaker:, Q:Classify K2O BF3. X Well begun is half done. Thunderlord Nova Mortis Abbadon, Solution A has a pH value of 5.6 and solution B has a pH value of 2.7. Expert Answer 100% (2 ratings) CH3NH3NO3 is a salt produced by the neutralization reaction between methyl amine CH3NH2 (a weak base) and ni View the full answer Previous question Next question 10 years ago. Get access to this video and our entire Q&A library, Acidic & Basic Salt Solutions: Explanation & Examples. Some of these constituent ion species may undergo further hydrolysis if they have appreciable acidic/basic, redox, or other relevant properties. If it cannot be ignored, you can solve for x with the quadratic formula. To neutalize an acid with a base you must put the base in the acid, that will give the substance pH of 7 which is neutral. 1st beaker: Draw HF, a weak acid copyright 2003-2023 Homework.Study.com. HNO2 + H2O NO2- + H3O+ 100 mL of 0.5 M H2SO4 A. Cleaner Explain. Is an aqueous solution with H3O+ = 2.93 x 10-6 M acidic, basic, or neutral? d. HAsO42-is an acid and AsO43-is its conjugate base. Is ch3nh2 acid or base? What are the differences between a male and a hermaphrodite C. elegans? Answer: In short CH3CH2NH3Cl is acidic because it is formed from a strong acid (HCl) and a weak base (CH3CH2NH2). Modified by Tom Neils (Grand Rapids Community College). These contour maps demonstrate that the smallest, most highly charged metal ion (\(Al^{3+}\)) causes the greatest decrease in electron density of the OH bonds of the water molecule. (6) CH3NH2 and CH3NH3C1 Yes, this could be a buffer. View Available, Q:Explain why an acid-base reaction will only proceed if the products formed are weaker conjugate acid, A:Answer: Explain. 1 Answer. Adresse:Calea Grivitei, 2-2A, 1st District, Bucharest, 2020 FABIZ - Bucharest University of Economic Studies, Algebra 2 Assignment Factor Each Completely Kuta Software, Unscramble Sentences Worksheets For Kindergarten, Master in Entrepreneurship and Business Administration (MEBA), Master en Entrepreneuriat et Gestion des Affaires (MEGA), Master in Entrepreneurship und Betriebswirtschaft (MEBW), Master in Digital Business and Innovation (MDBI), International Master in Business Administration (IMBA), Master of Entrepreneurship and Business Administration in Energy (Energy MBA). Question: Hydroxylamine (HONH2) is a weak base. Making educational experiences better for everyone. To tell if AlCl3 (Aluminum chloride) forms an acidic, basic (alkaline), or neutral solution we can use these three simple rules along with the neutralization reaction that formed AlCl3 .First we need to figure out the acid and base that were neutralized to form Aluminum chloride. Relevance. Is an aqueous solution with H3O+ = 4.91 x 10-4 M acidic, basic, or neutral? Mtg First Strike Rules, Which of the following is a neutralization reaction? acid base or neutral help? Then substitute into the log part. Label the acid, base, conjugate acid and, A:Acid which release H+ in the reaction and base which gain H+ from acid reaction (c) Potassium hydrogen sulfate (also called potassium bisulfate) is an acidic salt. Explain. The \(H_3O^+\) concentration produced by the reactions is great enough, however, to decrease the \(pH\) of the solution significantly: the \(pH\) of a 0.10 M solution of ammonium chloride or pyridinium chloride at 25C is 5.13 or 3.12, respectively. The order in which you list the products does not matter. Show the formation of the conjugate acid from So the compound CH3NH3ClO4 is somewhat acidic. HSO4- Match each of the solutions with the measured pH values. 22 6.2K views 2 years ago To tell if FeBr3 (Iron (III) bromide) forms an acidic, basic (alkaline), or neutral solution we can use these three simple rules along with the neutralization reaction. CH3NH3NO3. Its pH is around 5.4. The pH of an aqueous solution of 0.340 M methylamine (a weak base with the formula CH_3NH_2) is _____. A water molecule coordinated to a metal ion is more acidic than a free water molecule for two reasons. Explain. Solutions of small, highly charged metal ions in water are acidic. The contours show the electron density on the O atoms and the H atoms in both a free water molecule (left) and water molecules coordinated to \(Na^+\), \(Mg^{2+}\), and \(Al^{3+}\) ions. Is an aqueous solution with H3O+ = 9.15 x 10-6 M acidic, basic, or neutral? 9 years ago. If, however, the anion is the conjugate base of a weak acid, the solution will be basic. AgCl(s) + HNO3(aq) Similary, H3O+ is an acid as it can now donate a proton but it is a conjugate acid to the base H2O Find out more about how we use your information in our Privacy Policy and Cookie Policy. Conjugate Acid If you consider the species in this chemical reaction, two sets of similar species exist on both sides. {/eq} will be: A. basic, because of the hydrolysis of NO{eq}_3^- A 0.150MM solution of morphine has a pHpH of 10.5.What isKbKb for. Figure \(\PageIndex{1}\): Effect of a Metal Ion on the Acidity of Water (a) Reaction of the metal ion \(Al^{3+}\) with water to form the hydrated metal ion is an example of a Lewis acidbase reaction. Given that, The reaction of a salt with water to produce an acidic or a basic solution is called a hydrolysis reaction. The conjugate acid of HC3NH2 is CH3NH3^1+ What strong acid and strong base produce sodium sulfate?. Explain. The \(K^+\) cation has a small positive charge (+1) and a relatively large radius (because it is in the fourth row of the periodic table), so its K, The \(NO_3\) anion is the conjugate base of a strong acid, so it has essentially no basic character (K. Hence neither the cation nor the anion will react with water to produce \(H^+\) or \(OH^\), and the solution will be neutral. Favorite Answer. Is an aqueous solution with H3O+ = 8.69 x 10-9 M acidic, basic, or neutral? D. Would a 0.1 M aqueous solution of ZnCl2 be acidic, basic, or neutral? What I reason: Calcium chloride is the salt of hydrochloric acid and calcium hydroxide. For example, ammonium chloride and pyridinium chloride are salts produced by reacting ammonia and pyridine, respectively, with \(HCl\). Will an aqueous solution of Li2S be acidic, basic, or neutral? Is an aqueous solution with H3O+ = 4.10 x 10-5 M acidic, basic, or neutral? Victor. a. HAsO42-is an acid and H2O is its conjugate base. Conversely, if the cation is a weaker acid than the anion is a base, the final solution has a \(pH\) > 7.00. The \(Cl^\) ion is the conjugate base of the strong acid \(HCl\), so it has essentially no basic character (Kb < 1 x 10-14). Acid is a substance which donates proton, Q:List 3 other substances that you can use (instead of Sweet Tarts or milk) to Explain. Each acid and each base has an associated ionization constant that corresponds to its acid or base strength. https://www.thinglink.com/scene/636594447202648065 ACID ( wikipedia) An acid is a molecule or ion capable of donating a hydron (proton or hydrogen ion H+), or, alternatively, capable of forming a covalent bond with an electron pair (a Lewis acid). What is the pH of a 0.350 M solution of sodium bicarbonate? Is an aqueous solution with H3O+ = 1.34 x 10-4 M acidic, basic, or neutral? This salt is acidic. Explain. It has an empty 3pz orbital that accepts electron density, making it an electron pair acceptor, a Lewis acid. C2H5NH3NO3 is weakly acidic because the cation is the conjugate acid of the weak base ethylamine. Is an aqueous solution with H+ = 1.08 x 10-6 M acidic, basic, or neutral? These two species can undergo a Lewis acid-base reaction. To enable Verizon Media and our partners to process your personal data select 'I agree', or select 'Manage settings' for more information and to manage your choices. We have to compare both the solutions', Q:Write the net ionic equation for the acid-base hydrolysis equilibrium that is established when, Q:What is the relationship between Is an aqueous solution with H3O+ = 9.29 x 10-5 M acidic, basic, or neutral? NH4Cl produces ammonia and chloride ions. Reactions such as those discussed in this section, in which a salt reacts with water to give an acidic or basic solution, are often called hydrolysis reactions. Since CH3NH3NO3 is an acid, you convert the 5.2 x 10-4 through dividing by 1.0 x 10-14 to get ka Then you use the normal calculations and multiply ka If a substance has a pH lower than 7, it is an acid. Explanation: Remove H+ from C2H5OH and we get C2H5O , ethoxide anion. Will a solution of CH3NH3NO3 be acidic, basic or neutral? In chemistry, a salt is an ionic compound that can be formed by the neutralization reaction of an acid and a base. CH3NH2 is a stronger base as NH3. AGNO3(aq) + HCl(aq) In aqueous solution, classify these compounds as strong acids, weak acids, strong bases, weak bases, or other. CH3NH2 is not a strong base. Chloride ions come from HCl, hydrochloric acid, a strong acid. Question = Is if4+polar or nonpolar ? I'll tell you the Acid or Base list below. Conjugate Acid CH3NH3+ acts as a acid because Brnsted-Lowry acids give away a proton. It is formed from the neutralization of strong acid, namely Nitric acid (HNO 3) with a weak base, namely Ammonium hydroxide (NH 4 OH). Note that there is no $\ce {OH-}$ to start with (very little in reality), so equation $ (1)$ is not applicable. Is an aqueous solution with H3O+ = 8.85 x 10-5 M acidic, basic, or neutral? Depending on the acidbase properties of its component ions, a salt can dissolve in water to produce a neutral solution, a basic solution, or an acidic solution. Explain. Explain. This salt is acidic. Q:Calculate the concentration of OH-(aq) in a solution in which [H3O+] is 2 10-6M. Q:Now, on a separate sheet of paper, draw three beakers. Salts are composed of related numbers of cations (positively charged ions) and anions (negative ions) so that the product is electrically neutral (without a net charge). Likewise CH3NH3+ is the conjugate acid of the weak base, methylamine (CH3NH2). Which statement is correct, Q:Which of the following are likely to act as Lewis acids and which as Lewis bases? Explain. (b) Potassium perchlorate, KClO4, is a neutral salt. Most questions answered within 4 hours. c) it cannot hold on to its hydroxide ions. For example, ammonium chloride, NH 4 Cl, is a salt formed by the reaction of the weak base ammonia with the strong acid HCl: NH3(aq)+HCl(aq) NH4Cl(aq) NH 3 ( a q) + HCl ( a q) NH 4 Cl ( a q) A solution of this salt contains ammonium ions and chloride ions. pH of the mixed, Q:What is the conjugate base of HSO4 ? Calcium hydroxide is usually not considered a strong base, and I believe this is because of it's low solubility. Al(NO3)3 is strongly acidic because Al3+ is a Lewis acid. Is an aqueous solution with H3O+ = 7.93 x 10-5 M acidic, basic, or neutral? light leaves, dark sees lyrics; https emerge asurehcm com sysforms login aspx; ch3nh3 acid or base. A:A salt made from strong base and weak acid give basic aqueous solution. Explain. Is Z n S O 4 in aqueous solution acidic or basic? Our videos will help you understand concepts, solve your homework, and do great on your exams. Predict whether aqueous solutions of the following are acidic, basic, or neutral. Is h3po4 a strong acid? Ammonium nitrite, NH4NO2, is the ammonium salt of nitrous acid. Lv 7. Donottry to enter any physical states or coefficients in the answer boxes. Methylamine (CH_3NH_2) forms hydroxide ions in aqueous solution. Ca(HCOO)2 == HCOO- reacts with water to make a basic solution. H3PO4is an acid and PO43-is its conjugate base *Response times may vary by subject and question complexity. HClO4is the acid and H3SO4+is its, A:Given: {/eq}NH{eq}3^+ LIST ACID NH4ClO4 NH4Cl HBrO (WEAK) H2PO4- H3PO3 (WEAK) HNO3 (STRONG) HCl (STRONG) H2S (WEAK) H2SO4 (STRONG) H3PO4 (WEAK) H2CO3 (WEAK) HBr (STRONG HI (STRONG) HClO4 (STRONG) Explain. All rights reserved. Information about your device and internet connection, including your IP address, Browsing and search activity while using Verizon Media websites and apps. Explain. (Use H3O+ instead of H.) Is the solution acid, basic, or neutral? NH4NO2 + HOH ==> HNO2 + NH4OH Note that HNO2 is a weak acid and NH4OH actually is NH3 + H2O (a weak base); therefore, the decision rests upon which is stronger, the weak acid or the weak base. Relative strengths of weak acids. Again, the cations (\(K^+\) and \(Na^+\)) have essentially no acidic character, but the anions (\(CN^\) and \(CH_3CO_2^\)) are weak bases that can react with water because they are the conjugate bases of the weak acids \(HCN\) and acetic acid, respectively and they have Ka > 1 x 10-14. Kb for hypoiodite ion = 0.00044. Acetone is a weak Lewis base that forms adducts with soft acids like I2 and hard acids like phenol. NaCl + AgNO3 =, A:Reaction between silver nitrate and sodium chloride is a double replacement reaction. Start your trial now! Now you can set up your ICE table for the acid dissociation in eqn (1) above: Initial 0.8000, Change -x+x+x, Equilibrium 0.80-xxx. This cookie is set by GDPR Cookie Consent plugin. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Explain. However, we know that for a weak acid and its conjugate base, the relationship of Ka to Kb is, (2) KaKb=Kw, where Kw = 10-14 is the dissociation constant of water, H2O H+ + OH- (if you are studying acid-base equilibria, it is a really good idea to memorize Kw !! Sodium bicarbonate is the conjugate base of carbonic acid. a. The methylammonium cation CH3NH3+ is similar to the ammonium (NH4+) which is somewhat acidic due to it being the conjugate acid of a weak base (NH3). The aqueous solution of KC2H3O2 K C 2 H 3 O 2 is basic in nature since a hydroxide ion is produced during the reaction. D. Coffee. List molecules Acid and Base. Question = Is ICl3polar or nonpolar ? An aqueous solution of CH3NH3NO3 will be Group of answer choices A. basic, because of the hydrolysis of NO3 ions. A 50:50 mixture means base and acid or equal so base/acid = 1 and log 1 = 0; therefore, pH = pKa and you will know acid or base Polar "In chemistry, polarity is Is CH3NH3NO3 an acid or base or neutral ? 1. Making educational experiences better for everyone. Formula ofoneproduct (do not include the coefficient):Answer For Free. Will an aqueous solution of NH_3 be acidic, neutral or basic? So CH3NH3+ has acidic properties. Methylamine, CH3NH2, is a weak base that reacts according to the following equation. According to Bronsted and Lowry concept, an acid is a substance that can donate, Q:a. Choose an expert and meet online. Is an aqueous solution with H3O+ = 5.18 x 10-5 M acidic, basic, or neutral? Volume of Potassium hydroxide = 47.9 mL Why is methylamine a Bronested-Lowry base but not an Arrhenius base? This conjugate acid is a weak acid. Asked for: acidity or basicity of aqueous solution. pH = look up the value of Ka (and convert to pKa) or pKa C6H5COOH and substitute for pKa in the equation. If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. D. basic, because of the hydrolysis of CH{eq}3 Ca(HCOO)2 . Explain. You can also neutralize a base with an acid, but putting the. What would be the coefficient in front of the KOH in the balanced equation for the reaction? A hydrolysis reaction is an acidbase reaction. These cookies will be stored in your browser only with your consent. LiC2H3O2. What is the conjugate acid of CH3NH2? Chemists use the negative of the logarithm of the concentration of hydrogen ions to define the pH scale. Explain. It includes a weak base and the salt of that weak base. Is an aqueous solution with H3O+ = 8.53 x 10-4 M acidic, basic, or neutral? CH3NH2 is a base. Amines react as {Blank} (acid, base, or neutral) in aqueous solution. 2. Answer = CLO3- (Chlorate) is Polar What is polarand non-polar? Neither reaction proceeds very far to the right as written because the formation of the weaker acidbase pair is favored. Assess the acidbase properties of the cation and the anion. Instead, they react with water to generate OH- ions. Why? 8 years ago. base CH3NH2 (analogous to NH4. (Report a single digit for your answer. Would an aqueous solution with H+ = 5.3 x 10-5 M be acidic, basic, or neutral? Is an aqueous solution with H3O+ = 5.74 x 10-4 M acidic, basic, or neutral? It is a buffer, since while adding H ions to K3PO4 (or OH ions to H3PO4) solution you are forming the conjugate base/acid (K2HPO4 for K3PO4 and KH2PO4 for H3PO4) salts in the solution, which is the description of buffer. The Ka for NH4+ can be found by Kw/(Kb for NH3) and the Kb for NO2- can be found by Kw/(Ka for HNO2). Determine the pH of a 0.50-M solution of NH4OCl. Express your answer as a chemical formula. Methylamine forms salts such as methylammonium nitrate, CH3NH3NO3. What happens with aqueous solutions of a salt such as ammonium acetate, where both the cation and the anion can react separately with water to produce an acid and a base, respectively? H2O is an acid and H3O+is its conjugate base Explain. b) Explain why it is the stronger base. My thesis aimed to study dynamic agrivoltaic systems, in my case in arboriculture. Acetic acid (CH3COOH) is a weak acid. Is an aqueous solution with H3O+ = 8.45 x 10-9 M acidic, basic, or neutral? Along with it, barium bromide reacts with oxygen, sulfur, and carbon to form barium compounds. Explain and justify your answer clearly. acid-base reactions? Is an aqueous solution with H3O+ = 4.52 x 10-8 M acidic, basic, or neutral? B. HCL solution b., Q:In the reversible equation: A base is defined as a proton acceptor or lone pair donor. Explain. Is an aqueous solution with H3O+ = 3.85 x 10-8 M acidic, basic, or neutral? CHs Take the -log of[H+] and you will have the pH of the solution. Is an aqueous solution with H3O+ = 0.0000830 M acidic, basic, or neutral? c. it cannot hold on to its H+ ions. Is an aqueous solution with H3O+ = 6.31 x 10-8 M acidic, basic, or neutral? Explain. 2.0x10-11 = (x)(x)/(0.0850 - x) and assuming x is small compared to 0.0850 we can ignore it. In chemistry, reaction is always expected to proceed in the direction where, substances are, Q:Directions: Write the correct Lewis structure and show the step-by-step solution on how you came up, A:The concept of covalent bond is explained Lewis. Is an aqueous solution with H3O+ = 0.000745 M acidic, basic, or neutral? In, Q:Which of the following compounds will form a basic solution when dissolved in water? Is an aqueous solution with H+ = 8.60 x 10-10 M acidic, basic, or neutral? The chloride ion has no effect on the acidity of the . mason jars canada; deion sanders super bowl rings; cancer no symptoms reddit; can you walk across the robert f kennedy bridge CH3Li and CH3MgBr can therefore be thought of as a source of the CH3- ion. Br Is an aqueous solution with H+ = 6.8 x 10-8 M acidic, basic, or neutral? Explain. RbBr == does not hydrolyze, neutral (CH3)2NH2Cl == (CH3)2NH2 reacts with Answer = if4+ isPolar What is polarand non-polar? If the cation is a weak Lewis acid, it will not affect the \(pH\) of the solution. Yes, they're bigger and "badder" then most other salts. For metal ions with the same charge, the smaller the ion, the shorter the internuclear distance to the oxygen atom of the water molecule and the greater the effect of the metal on the electron density distribution in the water molecule. However, you may visit "Cookie Settings" to provide a controlled consent. Consider the following four aqueous solutions: NaBr(aq), K_2SO_3(aq), NH_4Cl(aq), and Cr(NO_3)_3(aq). In chemistry, a salt is an ionic compound that can be formed by the neutralization reaction of an acid and a base.
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